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Antiscattering X-ray fluorescence analysis for large-area samples

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Abstract

Polarized X-rays have been utilized for many years to reduce the scattering background and optimize the signal-to-background ratio in the measurement of X-ray fluorescence spectra. It is vital to set a small solid angle in the direction of polarization for collecting fluorescence X-rays and scattering X-rays from a sample. Conventionally, this is realized by employing a large sample-to-detector distance and limiting the size of the probing area on the sample and the opening area of the detector. In this work, a collimator plate that assembles many parallel straight hollow capillaries is inserted between the sample and the detector. This can improve the signal-to-background ratio by tens of times when the primary X-rays have a high degree of polarization. The probing area on the sample is as large as 13.3 × 13.3 mm, making it convenient to survey trace elements dispersed in large-area environmental samples and industrial products. The sample-to-detector distance is as short as 3 mm, making the instrument compact and applicable to low-Z elements. The present polarization-collimator experimental scheme can exhibit its maximum potential in combination with strong and highly polarized synchrotron radiation with a reasonably large beam size.

Graphical abstract: Antiscattering X-ray fluorescence analysis for large-area samples

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Publication details

The article was received on 24 Jun 2019, accepted on 20 Aug 2019 and first published on 24 Sep 2019


Article type: Paper
DOI: 10.1039/C9JA00220K
J. Anal. At. Spectrom., 2019, Advance Article
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    Antiscattering X-ray fluorescence analysis for large-area samples

    W. Zhao, K. Hirano and K. Sakurai, J. Anal. At. Spectrom., 2019, Advance Article , DOI: 10.1039/C9JA00220K

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