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Synthesis of long-chain polyols from the Claisen condensation of γ-valerolactone

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Abstract

A novel and direct method for the production of polyols with long chains is developed under simple and mild conditions starting from renewable gamma-valerolactone (GVL), a chemical platform easily obtained from biomass. The key step involves a Claisen condensation between two GVL molecules to provide a cyclic hemiketal in 85% yield. After alkylation and/or reduction, this ketal serves as a new platform to produce several high-value-added branched chain molecules with carbons ranging from C10 to C21.

Graphical abstract: Synthesis of long-chain polyols from the Claisen condensation of γ-valerolactone

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Publication details

The article was received on 24 Sep 2019, accepted on 22 Oct 2019 and first published on 22 Oct 2019


Article type: Paper
DOI: 10.1039/C9GC03343B
Green Chem., 2019, Advance Article

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    Synthesis of long-chain polyols from the Claisen condensation of γ-valerolactone

    C. S. Santos, C. C. S. P. Soares, A. S. Vieira and A. C. B. Burtoloso, Green Chem., 2019, Advance Article , DOI: 10.1039/C9GC03343B

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