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Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt-molybdenum catalysts

Abstract

Nitrogen-doped carbon supported cobalt-molybdenum bimetallic catalysts (abbreviated as Co-Mo/NC) were active for the hydrodeoxygenation of sulfoxides to sulfides under mild conditions (25~80 °C and 10 bar H2), which represented the first example on the use of heterogeneous non-noble metal catalysts for this transformation. MoO3 as Lewis acid sites assisted the hydrodeoxygenation of sulfoxides into sulfides by hydrogen over cobalt nanoparticles.

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Publication details

The article was received on 18 Jul 2019, accepted on 12 Nov 2019 and first published on 20 Nov 2019


Article type: Communication
DOI: 10.1039/C9GC02465D
Green Chem., 2019, Accepted Manuscript

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    Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt-molybdenum catalysts

    K. Yao, Z. Yuan, S. Jin, Q. Chi, B. Liu, R. Huang and Z. Zhang, Green Chem., 2019, Accepted Manuscript , DOI: 10.1039/C9GC02465D

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