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Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts

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Abstract

Nitrogen-doped carbon-supported cobalt–molybdenum bimetallic catalysts (abbreviated as Co–Mo/NC) are active for the hydrodeoxygenation of sulfoxides to sulfides under mild conditions (25–80 °C and 10 bar H2), which represents the first example of the use of heterogeneous non-noble metal catalysts for this transformation. MoO3 with Lewis acid sites assists the hydrodeoxygenation of sulfoxides into sulfides by hydrogen over cobalt nanoparticles.

Graphical abstract: Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts

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Publication details

The article was received on 18 Jul 2019, accepted on 12 Nov 2019 and first published on 20 Nov 2019


Article type: Communication
DOI: 10.1039/C9GC02465D
Green Chem., 2019, Advance Article

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    Efficient hydrodeoxygenation of sulfoxides into sulfides under mild conditions using heterogeneous cobalt–molybdenum catalysts

    K. Yao, Z. Yuan, S. Jin, Q. Chi, B. Liu, R. Huang and Z. Zhang, Green Chem., 2019, Advance Article , DOI: 10.1039/C9GC02465D

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