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Ionic liquids tethered to a preorganised 1,2-diamide motif for extraction of lanthanides

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Abstract

New preorganised 1,2-diamide functionalised, bidentate ligand-embedded hydrophobic ionic liquids (DAILs) were synthesised, which enabled efficient extraction of lanthanides from an aqueous phase. The selective metal binding ability of the functionalised ionic liquid was examined by NMR, FTIR and a structure optimisation calculation. The selective liquid–liquid extraction behavior with DAILs was demonstrated.

Graphical abstract: Ionic liquids tethered to a preorganised 1,2-diamide motif for extraction of lanthanides

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Publication details

The article was received on 09 Jan 2019, accepted on 18 Mar 2019 and first published on 26 Mar 2019


Article type: Communication
DOI: 10.1039/C9GC00089E
Green Chem., 2019, Advance Article

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    Ionic liquids tethered to a preorganised 1,2-diamide motif for extraction of lanthanides

    R. Boyd, L. Jin, P. Nockemann, P. K. J. Robertson, L. Stella, R. Ruhela, K. R. Seddon and H. Q. N. Gunaratne, Green Chem., 2019, Advance Article , DOI: 10.1039/C9GC00089E

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