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Metallomicelle catalyzed aerobic tandem desilylation/Glaser reaction in water

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Abstract

PEG-grafted nitrogen ligands were synthesized. The corresponding copper complexes serve as metallomicellar nanoreactors for the aerobic tandem desilylation/Glaser coupling of TMS-protected alkynes in water. The protocol is also suitable for base-free homocoupling of terminal alkynes. The metallomicellar catalyst could be recycled 5 times with minor loss of reactivity.

Graphical abstract: Metallomicelle catalyzed aerobic tandem desilylation/Glaser reaction in water

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Publication details

The article was received on 06 Dec 2018, accepted on 21 Mar 2019 and first published on 25 Mar 2019


Article type: Communication
DOI: 10.1039/C8GC03815E
Citation: Green Chem., 2019, Advance Article

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    Metallomicelle catalyzed aerobic tandem desilylation/Glaser reaction in water

    S. Tang, L. Li, X. Ren, J. Li, G. Yang, H. Li and B. Yuan, Green Chem., 2019, Advance Article , DOI: 10.1039/C8GC03815E

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