Status and Challenges in Photocatalytic Nanotechnology for Cleaning Air Polluted with Volatile Organic Compounds: Visible Light Utilization and Catalyst Deactivation
Photocatalysis that utilizes semiconductor nanoparticles is one of the most investigated environmental nanotechnologies. It is a promising technology for air purification because it can decompose gaseous pollutants (particularly volatile organic compounds (VOCs)) directly into harmless CO2 and H2O under ambient conditions. Photocatalysis can be particularly suitable for removing low concentration pollutants (sub-ppm levels) in indoor environments where the conventional adsorption technologies are not very efficient. Although photocatalytic air purification has been extensively investigated, it still falls far short of satisfying requirements for practical usage. This review focuses on two main critical issues for improving the applicability of photocatalytic air purification: (1) increasing visible light activity to utilize ambient light and (2) preventing catalyst deactivation that hinders long-term usage of photocatalysts. The literature reports on the photocatalytic degradation of VOCs using visible light are surveyed and systematically categorized based on the type of photocatalytic materials and VOCs. Strategies taken to significantly increase the effciency of visible light photocatalysts are introduced. On the other hand, the photocatalyst deactivation processes are discussed according to the kind of air pollutants and various methods of assessing the extent of photocatalyst deactivation are outlined. The development of deactivation-resistant photocatalysts and their applications to air purification are also introduced and discussed. Finally, the status and the problems of the current research on photocatalytic air purification are critically discussed and the suggestions for future studies of photocatalytic air purification are made.