Jump to main content
Jump to site search


Revealing the Origin of Voltage Loss in Mixed-Halide Perovskite Solar Cells

Abstract

The tunable bandgap of metal-halide perovskites has opened up the possibility of tandem solar cells with over 30% efficiency. Iodide-Bromide (I-Br) mixed-halide perovskites are crucial to achieve the optimum bandgap for such tandems. However, when the Br content is increased to widen the bandgap, cells fail to deliver the expected increase in open-circuit voltage (VOC). This loss in VOC has been attributed to photo-induced halide segregation. Here, we combine Fourier Transform Photocurrent Spectroscopy (FTPS) with detailed balance calculations to quantify the voltage loss expected from the halide segregation, providing a means to quantify the VOC losses arising from the formation of low bandgap iodide-rich phases during halide segregation. Our results indicate that, contrary to popular belief, halide segregation is not the dominant VOC loss mechanism in Br-rich wide bandgap cells. Rather, the loss is dominated by the relatively low initial radiative efficiency of the cells, which arises from both imperfections within the absorber layer, and at the perovskite/charge extraction layer heterojunctions. We thus identify that focussing on maximising the initial radiative efficiency of the mixed-halide films and devices is more important than attempting to suppress halide segeregation. Our results suggest that a VOC of up to 1.33 V is within reach for a 1.77 eV bandgap perovskite, even if halide segregation cannot be supressed

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Jul 2019, accepted on 26 Nov 2019 and first published on 26 Nov 2019


Article type: Paper
DOI: 10.1039/C9EE02162K
Energy Environ. Sci., 2019, Accepted Manuscript

  •   Request permissions

    Revealing the Origin of Voltage Loss in Mixed-Halide Perovskite Solar Cells

    S. Mahesh, J. M. Ball, R. D. J. Oliver, David. P. McMeekin, P. Nayak, M. B. Johnston and H. Snaith, Energy Environ. Sci., 2019, Accepted Manuscript , DOI: 10.1039/C9EE02162K

Search articles by author

Spotlight

Advertisements