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Issue 48, 2019
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A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

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Abstract

We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal–metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer–Schuster rearrangement.

Graphical abstract: A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

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Publication details

The article was received on 11 Nov 2019, accepted on 14 Nov 2019 and first published on 15 Nov 2019


Article type: Communication
DOI: 10.1039/C9DT04366G
Dalton Trans., 2019,48, 17704-17708
  • Open access: Creative Commons BY-NC license
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    A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

    D. M. Knoll, C. Zippel, Z. Hassan, M. Nieger, P. Weis, M. M. Kappes and S. Bräse, Dalton Trans., 2019, 48, 17704
    DOI: 10.1039/C9DT04366G

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