A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

Daniel M. Knoll; Christoph Zippel; Zahid Hassan; Martin Nieger; Patrick Weis; Manfred M. Kappes; Stefan Bräse

doi:10.1039/C9DT04366G

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A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone†

Daniel M. Knoll,

^a Christoph Zippel,

^a Zahid Hassan,

^a Martin Nieger,

^b Patrick Weis,

^d Manfred M. Kappes

^cd and Stefan Bräse

*^ae

Author affiliations

* Corresponding authors

^a Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany
E-mail: braese@kit.edu

^b Department of Chemistry, University of Helsinki, P.O. Box 55 A.I. Virtasen aukio 1, 00014 University of Helsinki, Finland

^c Institute of Nanotechnology, Karlsruhe Institute of Technology, Herman-vonHelmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

^d Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-HaberWeg 2, 76131 Karlsruhe, Germany

^e Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Herman-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

We report the synthesis and catalytic application of a highly stable distance-defined Au/Ru heterobimetallic complex. [2.2]Paracyclophane serves as a backbone, holding the two metal centers in a spatial orientation and metal–metal fixed distance. The Au/Ru heterobimetallic complex is highly stable, easily accessible and exhibits promising catalytic activity in a visible-light mediated dual Au/Ru Meyer–Schuster rearrangement.

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DOI: https://doi.org/10.1039/C9DT04366G
Article type: Communication
Submitted: 11 Nov 2019
Accepted: 14 Nov 2019
First published: 15 Nov 2019
This article is Open Access

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Dalton Trans., 2019,48, 17704-17708

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A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

D. M. Knoll, C. Zippel, Z. Hassan, M. Nieger, P. Weis, M. M. Kappes and S. Bräse, Dalton Trans., 2019, 48, 17704 DOI: 10.1039/C9DT04366G

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Dalton Transactions

A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone†

Abstract

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A highly stable, Au/Ru heterobimetallic photoredox catalyst with a [2.2]paracyclophane backbone

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