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Issue 48, 2019
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Two synthetic routes generate two isopolyoxoniobates based on {Nb16} and {Nb20}

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Abstract

Self-assembly reactions of the Lindqvist-ion salt K7HNb6O19·13H2O, SeO2, and [Cu(2,2′-bipy)]2+ give, depending on different routes, two isopolyoxoniobates based on {Nb16} and {Nb20}, respectively, which, as new members of the very limited isopolyoxoniobate family, are observed for the first time. Furthermore, the solution behavior was investigated to determine the stability of the {Nb16} cluster in water.

Graphical abstract: Two synthetic routes generate two isopolyoxoniobates based on {Nb16} and {Nb20}

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Publication details

The article was received on 24 Oct 2019, accepted on 19 Nov 2019 and first published on 20 Nov 2019


Article type: Communication
DOI: 10.1039/C9DT04147H
Dalton Trans., 2019,48, 17709-17712

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    Two synthetic routes generate two isopolyoxoniobates based on {Nb16} and {Nb20}

    Z. Liang, Y. Qiao, M. Li, P. Ma, J. Niu and J. Wang, Dalton Trans., 2019, 48, 17709
    DOI: 10.1039/C9DT04147H

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