Jump to main content
Jump to site search


A Facile Synthesis of Energetic Salts Based on Fully Nitroamino-functionalized [1,2,4]Triazolo[4,3-b][1,2,4]triazole

Abstract

A novel family of fully nitroamino-functionalized [1,2,4]triazolo[4,3-b][1,2,4]triazole-based energetic salts were synthesized. All salts were characterized by IR, multinuclear NMR spectroscopy, thermal analysis and elemental analysis. The crystal structure of salts 5, 6, and 7 were confirmed by single-crystal X-ray diffraction. The densities of these salts are between 1.65 (4) and 1.89 g cm-3 (3), whilst their oxygen balances are between -42.8% (7) and -11.3% (3). Theoretical performance calculations (Gaussian 09 and EXPLO 6.01) provided detonation pressures and velocities for the salts 2–7 in the ranges 27.6-41.1 GPa and 8519-9518 m s-1, respectively, which make them competitive energetic materials.

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 Sep 2019, accepted on 03 Dec 2019 and first published on 03 Dec 2019


Article type: Paper
DOI: 10.1039/C9DT03829A
Dalton Trans., 2019, Accepted Manuscript

  •   Request permissions

    A Facile Synthesis of Energetic Salts Based on Fully Nitroamino-functionalized [1,2,4]Triazolo[4,3-b][1,2,4]triazole

    C. Bian, W. Feng, Q. Lei, H. Huang, X. Li, J. Wang, C. Li and Z. Xiao, Dalton Trans., 2019, Accepted Manuscript , DOI: 10.1039/C9DT03829A

Search articles by author

Spotlight

Advertisements