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Cerium–carbon dative interactions supported by carbodiphosphorane

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Abstract

A set of complexes containing dative interactions between a rare-earth metal and carbon are reported. Complex 2, Br3Ce(CDP)(THF), with a Ce←C bond was synthesized by the reaction of CeBr3 with a carbon(0) ligand, carbodiphosphorane (CDP). More significantly, a trivalent cerium complex 3, [BrCe(CDP)2](BPh4)2, with two σ dative interactions C→Ce←C was also isolated, which represents an unusual example of two dative interactions formed with the same atom in a molecule. Furthermore, π donation by the second lone-pair electrons of the CDP ligand is rather weak. Single-crystal X-ray diffraction shows that the Ce–C bond lengths in these complexes are comparable with those in cerium(III)–carbene species. Density functional theory calculations support the dative interaction formation in these complexes and the strength of σ-donation in 3 is stronger than that in 2.

Graphical abstract: Cerium–carbon dative interactions supported by carbodiphosphorane

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Publication details

The article was received on 23 Sep 2019, accepted on 30 Sep 2019 and first published on 01 Oct 2019


Article type: Paper
DOI: 10.1039/C9DT03770E
Dalton Trans., 2019, Advance Article

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    Cerium–carbon dative interactions supported by carbodiphosphorane

    W. Su, S. Pan, X. Sun, L. Zhao, G. Frenking and C. Zhu, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT03770E

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