Jump to main content
Jump to site search

Issue 44, 2019
Previous Article Next Article

Facile synthesis of silver alkynide cluster and coordination polymers using picolinic acid as a co-ligand

Author affiliations

Abstract

We describe five 1D-coordination polymers and two discrete silver clusters consisting of alkynides and picolinic carboxylates as co-ligands. In some cases, DMSO or EtOH further solvated the structural motifs. Utilising the sterically demanding tri-isopropylsilyl acetylene afforded a tridecanuclear cluster that possessed an unprecedented core with a silver center surrounded by six octahedrally arranged silver atoms.

Graphical abstract: Facile synthesis of silver alkynide cluster and coordination polymers using picolinic acid as a co-ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 16 Sep 2019, accepted on 14 Oct 2019 and first published on 14 Oct 2019


Article type: Paper
DOI: 10.1039/C9DT03697K
Dalton Trans., 2019,48, 16518-16524
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Facile synthesis of silver alkynide cluster and coordination polymers using picolinic acid as a co-ligand

    A. K. Gupta and A. Orthaber, Dalton Trans., 2019, 48, 16518
    DOI: 10.1039/C9DT03697K

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements