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An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate

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Abstract

A novel tungstophosphate H12Na4K3[{Fe5O5(OH)2(OAc)2}2{W2-O2(OH)}{P2W14O54}2]·36H2O (1) containing an unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] unit has been successfully obtained and characterized by IR, TGA, magnetic susceptibility measurements and single-crystal X-ray diffraction. It shows a decameric FeIII molecular assembly formed through two {Fe5O23} subunits bridged by a {W2O3} motif.

Graphical abstract: An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate

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Publication details

The article was received on 02 Sep 2019, accepted on 29 Oct 2019 and first published on 29 Oct 2019


Article type: Communication
DOI: 10.1039/C9DT03524A
Dalton Trans., 2019, Advance Article

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    An unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] cluster sandwiched in the tetravacant tungstophosphate

    Z. Yang, Y. Wang, Z. Liang, J. Lu, P. Ma, J. Niu and J. Wang, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT03524A

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