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A novel photochromic hybrid containing trinuclear [Cd3Cl12]6− clusters and protonated tripyridyl-triazines

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Abstract

Incorporation of electron-deficient N-protonated 2,4,6-tri(4-pyridyl)-1,3,5-triazine (H3TPT) into electron-rich chlorocadmate leads to a novel organic–inorganic hybrid [H3TPT]2[Cd3Cl12] (1), which features as a trinuclear anionic cluster [Cd3Cl12]6− with one CdCl6 octahedron and two CdCl4 tetrahedra via edge-sharing mode and exhibits excellent photochromic performance with fast photoresponsive rate, obvious coloration contrast and high thermal stability.

Graphical abstract: A novel photochromic hybrid containing trinuclear [Cd3Cl12]6− clusters and protonated tripyridyl-triazines

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Publication details

The article was received on 28 Aug 2019, accepted on 24 Sep 2019 and first published on 24 Sep 2019


Article type: Communication
DOI: 10.1039/C9DT03494C
Dalton Trans., 2019, Advance Article

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    A novel photochromic hybrid containing trinuclear [Cd3Cl12]6− clusters and protonated tripyridyl-triazines

    P. Hao, C. Guo, J. Shen and Y. Fu, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT03494C

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