Issue 48, 2019

In situ synthesis of CuO nanoparticles over functionalized mesoporous silica and their application in catalytic syntheses of symmetrical diselenides

Abstract

A versatile and novel catalyst, CuO nanoparticles immobilized over functionalized mesoporous silica (nCuO-FMS), has been synthesized over an organically modified mesoporous silica framework following a facile synthetic route. The surface of the silica support (SBA-15) is first grafted with the 3-aminopropyl silane group and then further functionalized with tris(4-formylphenyl)amine. The reaction is performed in such a way that a few –CHO groups remain free for further functionalization. Finally, the CuO nanoparticles immobilized on mesoporous silica are obtained by a one pot reaction between the functionalized silica, 2-aminophenol and CuCl2. The product obtained has been used as a catalyst for the syntheses of symmetrical diselenides in the presence of KOH as the base and dimethyl sulphoxide (DMSO) as the solvent. The materials have been characterized thoroughly by X-ray powder diffraction, nitrogen adsorption–desorption studies, transmission electron microscopy, thermal analysis and different spectroscopic techniques. The Cu content of the sample has been determined by atomic absorption spectrophotometry (AAS). The products of the catalytic studies have been identified and estimated by NMR spectroscopy. Almost 78% isolated yield could be achieved at 363 K within 3 hours of the reaction and the catalyst, nCuO-FMS, can be recycled at least up to five catalytic cycles.

Graphical abstract: In situ synthesis of CuO nanoparticles over functionalized mesoporous silica and their application in catalytic syntheses of symmetrical diselenides

Supplementary files

Article information

Article type
Paper
Submitted
21 Aug 2019
Accepted
18 Nov 2019
First published
18 Nov 2019

Dalton Trans., 2019,48, 17874-17886

In situ synthesis of CuO nanoparticles over functionalized mesoporous silica and their application in catalytic syntheses of symmetrical diselenides

T. Das, R. Chatterjee, A. Majee, H. Uyama, D. Morgan and M. Nandi, Dalton Trans., 2019, 48, 17874 DOI: 10.1039/C9DT03418H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements