Issue 40, 2019
From the journal:

Dalton Transactions

Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes†

Wangyang Ma,a   Jing-Xuan Zhang, ORCID logo b   Zhenyang Lin, ORCID logo *b   T. Don Tilley ORCID logo c  and  Qing Ye ORCID logo *ad  

* Corresponding authors

a Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China
E-mail: yeq3@sustech.edu.cn

b Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

c Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, USA

d School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210089, China

Abstract

The mononuclear cyclic (alkyl)(amino)carbene (cAAC) supported titanium(III) chloride complex [(cAAC)2TiCl3] has been synthesized by treatment of free cAAC with TiCl3(THF)3. Further reduction of (cAAC)2TiCl3 with potassium graphite (KC8) afforded the desired (cAAC)2TiCl2 complex, which features a small S–T energy gap. Both complexes were structurally characterized and represent the first cAAC supported Ti complexes.

Graphical abstract: Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9DT03342D
Article type
Communication
Submitted
16 Aug 2019
Accepted
18 Sep 2019
First published
18 Sep 2019

Dalton Trans., 2019,48, 14962-14965

Author version available


Download author version (PDF)

Permissions

Request permissions

Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(II) complexes

W. Ma, J. Zhang, Z. Lin, T. D. Tilley and Q. Ye, Dalton Trans., 2019, 48, 14962 DOI: 10.1039/C9DT03342D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements