Synthesis, structural characterisation, and cytotoxicity studies of Bi, W, and Mo containing homo- and hetero-bimetallic polyoxometalates

Abstract

Three new and different homo- and hetero-bimetallic polyoxometalate (POM) species have been synthesised by simple one-pot synthetic methods utilising naturally occurring bismite (Bi₂O₃) (or Bi(NO₃)₃·5H₂O) and aryl sulfonic acids. The POM species isolated are (NH₄)₁₄[Bi₂W₂₂O₇₆]·14H₂O (1·14H₂O), (NH₄)[Bi(DMSO)₇][Mo₈O₂₆]·H₂O (2·H₂O) and [(NH₄)₄(Mo₃₆O₁₀₈(OH)₄·16H₂O)]·45H₂O (3·45H₂O). The compounds have been characterised by X-ray crystallography, energy dispersive X-ray spectroscopy (EDX), powdered X-ray diffraction (PXRD), mass spectrometry (ESI-MS), Raman spectroscopy, thermogravimetric (TGA) and ICP analyis. In vitro cytoxicity and proliferation studies conducted on 1 and 3, highlight the low toxicity of these species.