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Issue 39, 2019
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CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

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Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Graphical abstract: CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

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Article information


Submitted
28 Jul 2019
Accepted
03 Sep 2019
First published
04 Sep 2019

Dalton Trans., 2019,48, 14580-14584
Article type
Communication

CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

A. Kumar, P. Daw, N. A. Espinosa-Jalapa, G. Leitus, L. J. W. Shimon, Y. Ben-David and D. Milstein, Dalton Trans., 2019, 48, 14580
DOI: 10.1039/C9DT03088C

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