Jump to main content
Jump to site search


Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand

Author affiliations

Abstract

H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

Graphical abstract: Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Jul 2019, accepted on 02 Aug 2019 and first published on 05 Aug 2019


Article type: Communication
DOI: 10.1039/C9DT03003D
Dalton Trans., 2019, Advance Article

  •   Request permissions

    Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand

    C. Yao, T. Zhang, C. Zhou and K. Huang, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT03003D

Search articles by author

Spotlight

Advertisements