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Water-mediated proton conduction in Ni(ii) and Co(ii) benzenetriphosphonates

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Abstract

Two novel transition metal compounds, [Ni(4,4′-bipyH)2(H2O)4]·2(H4bmt)·9H2O (1) and [Co(4,4′-bipy)(H2O)4][Co(4,4′-bipyH)2(H2O)4]·2(H3bmt)·6H2O (2), have been synthesized. They possess continuous H-bond networks and high-density [PO3] groups, which give conductivity values in the order of 10−3 S cm−1 in a wide temperature range and 98% relative humidity.

Graphical abstract: Water-mediated proton conduction in Ni(ii) and Co(ii) benzenetriphosphonates

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Publication details

The article was received on 19 Jul 2019, accepted on 23 Aug 2019 and first published on 28 Aug 2019


Article type: Communication
DOI: 10.1039/C9DT02960E
Dalton Trans., 2019, Advance Article

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    Water-mediated proton conduction in Ni(II) and Co(II) benzenetriphosphonates

    L. Feng, Z. Pan, H. Zhou, M. Zhou and H. Hou, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT02960E

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