The stability of group 10 metal POCOP pincer complexes: decomposition/reconstruction pathways of the pincer backbone

Abstract

Organometallic chemists usually like to use the word robust to describe pincer ligand frameworks in metal pincer complexes. Although most transition metal pincer complexes are thermally stable, the pincer backbone frameworks can still decompose under certain circumstances. In order to explore the stability of the bis(phosphinite) (POCOP) pincer backbone in transition metal pincer complexes, group 10 metal POCOP pincer complexes were exposed to different nucleophilic and electrophilic conditions, respectively. It was found that the POCOP pincer backbone is stable under intermolecular nucleophilic conditions but cannot survive intramolecular nucleophilic attack; the POCOP pincer backbone is also stable under weak electrophilic conditions but the backbone can be completely destroyed by strong Lewis acids such as AlCl₃. Possible decomposition/reconstruction pathways of the POCOP pincer ligand framework were proposed.