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One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

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Abstract

A crown-ether appended N-heteroacene 1 was reduced in the presence of NaBPh4 to the radical anion 2 by accepting one electron transferred from both the cathode and BPh4 as a reductant. The obtained radical anion 2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.

Graphical abstract: One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

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Publication details

The article was received on 05 Jul 2019, accepted on 23 Jul 2019 and first published on 23 Jul 2019


Article type: Communication
DOI: 10.1039/C9DT02797A
Dalton Trans., 2019, Advance Article

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    One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

    K. Isoda, H. Takahashi, Y. Mutoh, N. Hoshino and T. Akutagawa, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT02797A

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