Issue 35, 2019
From the journal:

Dalton Transactions

One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion†

Kyosuke Isoda, ORCID logo *abc   Hinako Takahashi,b   Yuichiro Mutoh, ORCID logo d   Norihisa Hoshinoe  and  Tomoyuki Akutagawa ORCID logo e  

* Corresponding authors

a Program in Advanced Materials Science, Faculty of Engineering and Design, Kagawa University, 2217-20 Hayashi-cho, Takamatsu 761-0396, Japan
E-mail: k-isoda@eng.kagawa-u.ac.jp

b Division of Advanced Materials Science, Graduate School of Engineering, Kagawa University, 2217-20 Hayashi-cho, Takamatsu 761-0396, Japan

c Health Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2217-14 Hayashi-cho, Takamatsu 761-0395, Japan

d Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Tokyo 162-8601, Japan

e Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan

Abstract

A crown-ether appended N-heteroacene 1 was reduced in the presence of NaBPh4 to the radical anion 2 by accepting one electron transferred from both the cathode and BPh4– as a reductant. The obtained radical anion 2 can function as a radical anion ligand to bridge two sodium ions to self-assemble into one-dimensional helical coordination polymers.

Graphical abstract: One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

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Article information

DOI
https://doi.org/10.1039/C9DT02797A
Article type
Communication
Submitted
05 Jul 2019
Accepted
23 Jul 2019
First published
23 Jul 2019

Dalton Trans., 2019,48, 13125-13129

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One-dimensional single-helix coordination polymer self-assembled by a crown-ether appended-N-heteroacene radical anion

K. Isoda, H. Takahashi, Y. Mutoh, N. Hoshino and T. Akutagawa, Dalton Trans., 2019, 48, 13125 DOI: 10.1039/C9DT02797A

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