Issue 32, 2019
From the journal:

Dalton Transactions

[(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units†

Zhenyu Li,a   Caiping Liu,a   Jie Wu,b   Zian Lin ORCID logo b  and  Li Xu ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: xli@fjirsm.ac.cn

b Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian, China

Abstract

The reaction of Ir(CO)2(acac) (acac = acetylacetonate) and K5Bi4 in ethylenediamine (en) solution produces a new archetype of a 15-vertex deltahedral hybrid, [(η3-Bi3)2(IrCO)6(μ4-Bi)3]3− (1a), from the Bixx−-coordination aggregation of the [Ir(CO)]+ cationic units, providing a feasible route towards new hybrid compounds made by the combination of Zintl anions and transition-metal carbonyl clusters.

Graphical abstract: [(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units

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Article information

DOI
https://doi.org/10.1039/C9DT02559F
Article type
Communication
Submitted
18 Jun 2019
Accepted
11 Jul 2019
First published
12 Jul 2019

Dalton Trans., 2019,48, 12013-12017

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[(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units

Z. Li, C. Liu, J. Wu, Z. Lin and L. Xu, Dalton Trans., 2019, 48, 12013 DOI: 10.1039/C9DT02559F

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