Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N2O2- and N2O4-type dipyrrins

Akinobu Sumiyoshi; Yusuke Chiba; Ryota Matsuoka; Takumu Noda; Tatsuya Nabeshima

doi:10.1039/C9DT02403D

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Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N₂O₂- and N₂O₄-type dipyrrins†

Akinobu Sumiyoshi,^a Yusuke Chiba,

^a Ryota Matsuoka,

^a Takumu Noda^a and Tatsuya Nabeshima

*^a

Author affiliations

* Corresponding authors

^a Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: nabesima@chem.tsukuba.ac.jp

Abstract

The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N₂O₂/N₂O₄-type dipyrrins were synthesized and characterized. The N₂O₂-type complexes showed efficient luminescent properties even in polar solvents. The N₂O₄-type complexes exhibited fluorometric responses to alkaline earth metal ions.

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Article information

DOI: https://doi.org/10.1039/C9DT02403D
Article type: Paper
Submitted: 06 Jun 2019
Accepted: 28 Jun 2019
First published: 29 Jun 2019

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Dalton Trans., 2019,48, 13169-13175

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Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N₂O₂- and N₂O₄-type dipyrrins

A. Sumiyoshi, Y. Chiba, R. Matsuoka, T. Noda and T. Nabeshima, Dalton Trans., 2019, 48, 13169 DOI: 10.1039/C9DT02403D

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Dalton Transactions