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Issue 40, 2019
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Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study

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Abstract

B/N anionic aminoborane linear or branched chain complexes, [BH3(NH2BH2)nH] (n = 1, 2, and 3) and [BH(NH2BH3)3], have been synthesized through the controlled reactions of ammonia borane (NH3BH3) with NaH by adjusting the reactant ratios and reaction temperatures. The possible reaction mechanisms were elucidated based on experimental and theoretical studies.

Graphical abstract: Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study

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Publication details

The article was received on 30 May 2019, accepted on 27 Sep 2019 and first published on 28 Sep 2019


Article type: Communication
DOI: 10.1039/C9DT02289A
Dalton Trans., 2019,48, 14984-14988

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    Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH3BH3 with NaH and the mechanistic study

    X. Chen, J. Wang, S. Liu, J. Zhang, D. Wei and X. Chen, Dalton Trans., 2019, 48, 14984
    DOI: 10.1039/C9DT02289A

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