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Issue 34, 2019
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Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic activity towards microwave-assisted oxidation of xylenes

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Abstract

The new aroylhydrazone N′-(di(pyridin-2-yl)methylene)pyrazine-2-carbohydrazide (HL) species, rich in N-donor sites, has been used to synthesize Cu(II) compounds with different nuclearities, viz. the binuclear [Cu2(μ-1κN3,2κN2O-L)(Cl)3(MeOH)] (1), the octanuclear [Cu4(μ-1κN3,2κN2O-L)2(μ-Cl)3(Cl)3]2 (2) and the 1D coordination polymer [Cu33-1κN3,2κN2O,3κN-L)(μ-NO3)(NO3)3(H2O)3]n·nNO3 (3). They have been characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. The magnetic properties of 2 and 3 have been explored using variable temperature magnetic measurements. The catalytic performances of the compounds were evaluated towards the peroxidative oxidation of o-, p- and m-xylenes under microwave irradiation, leading to the formation of the corresponding methyl benzyl alcohol, tolualdehyde and toluic acid as the major products. Complex 3 exhibits the best catalytic activity towards the oxidation of p-xylene with a total yield of 37% (4-methylbenzyl alcohol + p-tolualdehyde + p-toluic acid).

Graphical abstract: Cu(ii) complexes of N-rich aroylhydrazone: magnetism and catalytic activity towards microwave-assisted oxidation of xylenes

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Publication details

The article was received on 24 May 2019, accepted on 15 Jul 2019 and first published on 15 Jul 2019


Article type: Paper
DOI: 10.1039/C9DT02196E
Dalton Trans., 2019,48, 12839-12849

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    Cu(II) complexes of N-rich aroylhydrazone: magnetism and catalytic activity towards microwave-assisted oxidation of xylenes

    M. Sutradhar, T. Roy Barman, E. C. B. A. Alegria, M. F. C. Guedes da Silva, C. Liu, H. Kou and A. J. L. Pombeiro, Dalton Trans., 2019, 48, 12839
    DOI: 10.1039/C9DT02196E

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