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Issue 41, 2019
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Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

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Abstract

A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.

Graphical abstract: Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

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Publication details

The article was received on 04 Jun 2019, accepted on 20 Jun 2019 and first published on 20 Jun 2019


Article type: Paper
DOI: 10.1039/C9DT02086A
Dalton Trans., 2019,48, 15465-15469

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    Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

    R. Torres-Cavanillas, L. Lima-Moya, F. D. Tichelaar, H. W. Zandbergen, M. Giménez-Marqués and E. Coronado, Dalton Trans., 2019, 48, 15465
    DOI: 10.1039/C9DT02086A

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