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Issue 29, 2019
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Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications

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Abstract

Tris(pyrazolyl)methane ligands (Tpmx) have been for years a step behind their highly popular boron-anionic analogues, the tris(pyrazolyl)borate ligands (Tpx). However, in the last decade the development of new members of this family of ligands has boosted a number of contributions albeit their use in coordination chemistry. This fact has also triggered the application of metal-Tpmx complexes as catalysts for a range of organic transformations, particularly with group 11 metals. The main structural features of complexes containing the TpmxM (M = Cu, Ag, Au) unit and their success as catalysts in a variety of reactions under homogeneous or heterogeneous conditions are presented.

Graphical abstract: Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications

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Article information


Submitted
19 Apr 2019
Accepted
21 May 2019
First published
22 May 2019

Dalton Trans., 2019,48, 10772-10781
Article type
Perspective

Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications

J. M. Muñoz-Molina, T. R. Belderrain and P. J. Pérez, Dalton Trans., 2019, 48, 10772
DOI: 10.1039/C9DT01661A

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