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Three new metal chalcogenide open frameworks built through co-assembly and/or hybrid assembly from supertetrahedral T5-InOS and T3-InS nanoclusters

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Abstract

Reported here are three new metal chalcogenide open frameworks built from supertetrahedral [In35S52O8] (denoted as T5-InOS or o-T5) and [In10S20] (denoted as T3-InS) nanoclusters of different sizes and compositions via co-assembly and/or hybrid assembly modes. Such a set of cluster-based superlattices with dia topological structures clearly exhibit quantum size effects and electronic coupling interaction of adjacent nanoclusters, which can effectively explain that the band gap of the T3–(o-T5) hybrid-assembled material lies in the middle of T3–T3 and (o-T5)–(o-T5) co-assembled materials.

Graphical abstract: Three new metal chalcogenide open frameworks built through co-assembly and/or hybrid assembly from supertetrahedral T5-InOS and T3-InS nanoclusters

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Publication details

The article was received on 03 Apr 2019, accepted on 25 Apr 2019 and first published on 25 Apr 2019


Article type: Communication
DOI: 10.1039/C9DT01410A
Dalton Trans., 2019, Advance Article

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    Three new metal chalcogenide open frameworks built through co-assembly and/or hybrid assembly from supertetrahedral T5-InOS and T3-InS nanoclusters

    J. Zhang, X. Liu, Y. Ding, C. Xue and T. Wu, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT01410A

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