Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.



Cooperative Catalysis at Metal-MOF Interface: Hydrodeoxygenation of Vanillin over Pd Nanoparticles Covered with UiO-66(Hf) MOF

Abstract

Cooperative catalysis has been demonstrated over metal-MOF hybrids for the conversion of vanillin (biomass based platform molecule) into value-added 4-hydroxy-3-methoxybenzaldehyde. Over Pd@UiO-66(Hf) core-hsell catalyst, cooperativity between Brønsted acidic μ3-OH groups and Pd active sites present at the interface has rendered a catalytic performance of >99% vanillin conversion and >99% 2-methoxy-4-methylphenol selectivity at 90 ˚C under 3 bar H2 in water. Enhanced cooperative effect has been observed over core-shell catalyst compared to support catalyst.

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 Mar 2019, accepted on 16 May 2019 and first published on 17 May 2019


Article type: Communication
DOI: 10.1039/C9DT01371G
Dalton Trans., 2019, Accepted Manuscript

  •   Request permissions

    Cooperative Catalysis at Metal-MOF Interface: Hydrodeoxygenation of Vanillin over Pd Nanoparticles Covered with UiO-66(Hf) MOF

    V. R. Bakuru, D. Davis and S. B. Kalidindi, Dalton Trans., 2019, Accepted Manuscript , DOI: 10.1039/C9DT01371G

Search articles by author

Spotlight

Advertisements