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The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

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Abstract

A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.

Graphical abstract: The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

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Publication details

The article was received on 28 Mar 2019, accepted on 17 May 2019 and first published on 17 May 2019


Article type: Communication
DOI: 10.1039/C9DT01322A
Dalton Trans., 2019, Advance Article

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    The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

    T. Sugahara, T. Sasamori and N. Tokitoh, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT01322A

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