Jump to main content
Jump to site search


Metal–organic-framework derived Co–Pd bond is preferred over Fe–Pd for reductive upgrading of furfural to tetrahydrofurfuryl alcohol

Author affiliations

Abstract

Combined noble-transition metal catalysts have been used to produce a wide range of important non-petroleum-based chemicals from biomass-derived furfural (as a platform molecule) and have garnered colossal research interest due to the urgent demand for sustainable and clean fuels. Herein, we report the palladium-modified metal–organic-framework (MOF) assisted preparation of PdCo3O4 and PdFe3O4 nanoparticles encapsulated in a graphitic N-doped carbon (NC) matrix via facile in situ thermolysis. This provides a change in selectivity with superior catalytic activity for the reductive upgrading of biomass-derived furfural (FA). Under the optimized reaction conditions, the newly designed PdCo3O4@NC catalyst exhibited highly efficient catalytic performance in the hydrogenation of furfural, providing 100% furfural conversion with 95% yield of tetrahydrofurfuryl alcohol (THFAL). In contrast, the as-synthesized Pd–Fe3O4@NC afforded a THFAL yield of 70% after an 8 h reaction with four consecutive recycling tests. Based on different characterization data (XPS, H2-TPR) for nanohybrids, we can conclude that the presence of PdCo-Nx active sites, and the multiple synergistic effects between Co3O4 and Pd(II), Co3O4 and Pd0, as well as the presence of N in the carbonaceous matrix, are responsible for the superior catalytic activity and improved catalyst stability. Our strategy provides a facile design and synthesis process for a noble-transition metal alloy as a superior biomass refining, robust catalyst via noble metal modified MOFs as precursors.

Graphical abstract: Metal–organic-framework derived Co–Pd bond is preferred over Fe–Pd for reductive upgrading of furfural to tetrahydrofurfuryl alcohol

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Mar 2019, accepted on 09 May 2019 and first published on 09 May 2019


Article type: Paper
DOI: 10.1039/C9DT01190K
Dalton Trans., 2019, Advance Article

  •   Request permissions

    Metal–organic-framework derived Co–Pd bond is preferred over Fe–Pd for reductive upgrading of furfural to tetrahydrofurfuryl alcohol

    S. Pendem, S. R. Bolla, D. J. Morgan, D. B. Shinde, Z. Lai, L. Nakka and J. Mondal, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT01190K

Search articles by author

Spotlight

Advertisements