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Issue 17, 2019
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Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

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Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni2(μ-bit)4·2H2O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(II) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

Graphical abstract: Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

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Article information


Submitted
04 Mar 2019
Accepted
28 Mar 2019
First published
28 Mar 2019

Dalton Trans., 2019,48, 5520-5522
Article type
Communication

Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(II) centre: a convenient synthesis of Ni(II)-thiolate complexes

S. A. Al-Jibori, S. H. Ali, A. S. Al-Janabi, C. Wagner and G. Hogarth, Dalton Trans., 2019, 48, 5520
DOI: 10.1039/C9DT00953A

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