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Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(II) centre: a convenient synthesis of Ni(II)-thiolate complexes

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Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni2(μ-bit)4·2H2O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(II) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

Graphical abstract: Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

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Publication details

The article was received on 04 Mar 2019, accepted on 28 Mar 2019 and first published on 28 Mar 2019


Article type: Communication
DOI: 10.1039/C9DT00953A
Citation: Dalton Trans., 2019, Advance Article

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    Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(II) centre: a convenient synthesis of Ni(II)-thiolate complexes

    S. A. Al-Jibori, S. H. Ali, A. S. Al-Janabi, C. Wagner and G. Hogarth, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT00953A

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