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Isostructural iron(III) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties

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Abstract

Here we present two isostructural iron(III) spin crossover complexes with the same tridentate ligand and perchlorate or tetrafluoroborate as counter ion. Single crystal X-ray structures in the high spin and low spin state were obtained for both complexes. An abrupt spin transition above 100 K is observed with the transition temperature depending on the size of the anion.

Graphical abstract: Isostructural iron(iii) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties

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Publication details

The article was received on 25 Feb 2019, accepted on 12 Apr 2019 and first published on 12 Apr 2019


Article type: Communication
DOI: 10.1039/C9DT00846B
Dalton Trans., 2019, Advance Article

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    Isostructural iron(III) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties

    K. Dankhoff and B. Weber, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C9DT00846B

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