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Issue 22, 2019
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Regression analysis of properties of [Au(IPr)(CHR2)] complexes

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Abstract

New [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.

Graphical abstract: Regression analysis of properties of [Au(IPr)(CHR2)] complexes

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Publication details

The article was received on 25 Feb 2019, accepted on 26 Apr 2019 and first published on 07 May 2019


Article type: Paper
DOI: 10.1039/C9DT00841A
Dalton Trans., 2019,48, 7693-7703

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    Regression analysis of properties of [Au(IPr)(CHR2)] complexes

    R. M. P. Veenboer, L. M. Azofra, D. Gasperini, A. Collado, D. B. Cordes, A. M. Z. Slawin, L. Cavallo and S. P. Nolan, Dalton Trans., 2019, 48, 7693
    DOI: 10.1039/C9DT00841A

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