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Issue 22, 2019
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Regression analysis of properties of [Au(IPr)(CHR2)] complexes

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Abstract

New [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.

Graphical abstract: Regression analysis of properties of [Au(IPr)(CHR2)] complexes

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Supplementary files

Article information


Submitted
25 Feb 2019
Accepted
26 Apr 2019
First published
07 May 2019

Dalton Trans., 2019,48, 7693-7703
Article type
Paper

Regression analysis of properties of [Au(IPr)(CHR2)] complexes

R. M. P. Veenboer, L. M. Azofra, D. Gasperini, A. Collado, D. B. Cordes, A. M. Z. Slawin, L. Cavallo and S. P. Nolan, Dalton Trans., 2019, 48, 7693
DOI: 10.1039/C9DT00841A

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