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Issue 17, 2019
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Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

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Abstract

The structures of the heterobimetallic Ca/Li and Ba/Li amides [CaLi22-N(SiMe2H)2}4] and [Ba2Li22-N(SiMe2H)2}6], stabilised by metal⋯H–Si interactions, and that of a diphenylmethanide calcium salt, [Li(tmeda)2+·Ca(CHPh2)3(thf)], are presented. These well-defined, storable compounds are inert towards Et2O and thf.

Graphical abstract: Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

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Publication details

The article was received on 20 Feb 2019, accepted on 18 Mar 2019 and first published on 19 Mar 2019


Article type: Communication
DOI: 10.1039/C9DT00771G
Citation: Dalton Trans., 2019,48, 5500-5504

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    Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

    E. le Coz, H. Roueindeji, V. Dorcet, T. Roisnel, J. Carpentier and Y. Sarazin, Dalton Trans., 2019, 48, 5500
    DOI: 10.1039/C9DT00771G

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