Jump to main content
Jump to site search

Issue 15, 2019
Previous Article Next Article

Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands

Author affiliations

Abstract

The synthesis and characterization of a new family of isostructural {Fe6Ln} complexes, (pipH)3{Fe6Ln(shiH)3(shi)6}·1.5 pip·xH2O (Ln = Gd (1), Dy (2), Tb (3) and Y (4), pip = piperidine, and shi3− = salicylhydroxamic acid) is reported. The resulting compounds possess an exceptionally unique structure of a metallacrown-like motif while the overall complexes feature more the structure of metallacryptates. Magnetic studies are reported and reveal that the {Fe6Dy} analogue belongs to the single-molecule magnet (SMM) family.

Graphical abstract: Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands

Back to tab navigation

Supplementary files

Article information


Submitted
04 Feb 2019
Accepted
12 Mar 2019
First published
12 Mar 2019

Dalton Trans., 2019,48, 4779-4783
Article type
Communication

Slow relaxation of magnetization in a {Fe6Dy} complex deriving from a family of highly symmetric metallacryptands

A. A. Athanasopoulou, L. M. Carrella and E. Rentschler, Dalton Trans., 2019, 48, 4779
DOI: 10.1039/C9DT00552H

Social activity

Search articles by author

Spotlight

Advertisements