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Issue 14, 2019
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Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

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Abstract

Mn(I) complexes that enable metal–ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO)5 as a synthon in place of typical Mn(CO)5Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O–H, N–H, and even C–H bonds.

Graphical abstract: Pentacarbonylmethylmanganese(i) as a synthon for Mn(i) pincer catalysts

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Article information


Submitted
02 Feb 2019
Accepted
04 Mar 2019
First published
04 Mar 2019

Dalton Trans., 2019,48, 4467-4470
Article type
Communication

Pentacarbonylmethylmanganese(I) as a synthon for Mn(I) pincer catalysts

K. J. Kadassery and D. C. Lacy, Dalton Trans., 2019, 48, 4467
DOI: 10.1039/C9DT00529C

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