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Issue 26, 2019
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Generation of maghemite nanocrystals from iron–sulfur centres

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Abstract

Iron oxide nano-crystals 0.1–1.1 μm in diameter were generated on sulfur-doped amorphous carbon surfaces by electron beam irradiation of the novel 13e high-spin complex [Fe(4-methyl-1,2-benzenedithiolate)2][NHEt3] encapsulated in a triblock copolymer. Possible relevance to iron nano-mineralization from Fe–S ferredoxin proteins and iron dysregulation in neurological disorders is discussed.

Graphical abstract: Generation of maghemite nanocrystals from iron–sulfur centres

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Article information


Submitted
01 Feb 2019
Accepted
04 Mar 2019
First published
05 Apr 2019

This article is Open Access

Dalton Trans., 2019,48, 9564-9569
Article type
Communication

Generation of maghemite nanocrystals from iron–sulfur centres

S. Banerjee, A. Omlor, J. A. Wolny, Y. Han, F. Lermyte, A. E. Godfrey, P. B. O'Connor, V. Schünemann, M. Danaie and P. J. Sadler, Dalton Trans., 2019, 48, 9564
DOI: 10.1039/C9DT00514E

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