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Issue 19, 2019
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Strong stacking interactions of metal–chelate rings are caused by substantial electrostatic component

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Abstract

Symmetry Adapted Perturbation Theory (SAPT) analysis shows that stacking interactions of metal–chelate rings are stronger than stacking interactions of organic molecules due to much stronger electrostatic interactions caused by the presence of metals. Depending on the ligand, electrostatic component of chelate stacking can be stronger than dispersion component.

Graphical abstract: Strong stacking interactions of metal–chelate rings are caused by substantial electrostatic component

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Publication details

The article was received on 14 Jan 2019, accepted on 04 Apr 2019 and first published on 08 Apr 2019


Article type: Communication
DOI: 10.1039/C9DT00182D
Dalton Trans., 2019,48, 6328-6332

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    Strong stacking interactions of metal–chelate rings are caused by substantial electrostatic component

    D. P. Malenov and S. D. Zarić, Dalton Trans., 2019, 48, 6328
    DOI: 10.1039/C9DT00182D

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