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Issue 13, 2019
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Ge(II) cation catalyzed hydroboration of aldehydes and ketones

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Abstract

Well-defined germylene cations [(i-Bu)2ATI]GeOTf (4) and [(i-Bu)2ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).

Graphical abstract: Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

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Publication details

The article was received on 26 Dec 2018, accepted on 07 Feb 2019 and first published on 07 Feb 2019


Article type: Communication
DOI: 10.1039/C8DT05121F
Citation: Dalton Trans., 2019,48, 4094-4100

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    Ge(II) cation catalyzed hydroboration of aldehydes and ketones

    S. Sinhababu, D. Singh, M. K. Sharma, R. K. Siwatch, P. Mahawar and S. Nagendran, Dalton Trans., 2019, 48, 4094
    DOI: 10.1039/C8DT05121F

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