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One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

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Abstract

The one-dimensional coordination polymer composed of CuII and an organic radical bisPyTM displayed temperature dependent Jahn–Teller distortion, which is correlated to the π-conjugation mode at the ligand as well as the magnetic properties. The ferromangetic bisPyTM–CuII interaction was enhanced by the reorientation of the CuII dx2y2 orbital at low temperature.

Graphical abstract: One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

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Publication details

The article was received on 24 Dec 2018, accepted on 21 Jan 2019 and first published on 25 Jan 2019


Article type: Communication
DOI: 10.1039/C8DT05104F
Citation: Dalton Trans., 2019, Advance Article

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    One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

    S. Kimura, H. Uchida, T. Kusamoto and H. Nishihara, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT05104F

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