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Issue 21, 2019
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One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

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Abstract

The one-dimensional coordination polymer composed of CuII and an organic radical bisPyTM displayed temperature dependent Jahn–Teller distortion, which is correlated to the π-conjugation mode at the ligand as well as the magnetic properties. The ferromangetic bisPyTM–CuII interaction was enhanced by the reorientation of the CuII dx2y2 orbital at low temperature.

Graphical abstract: One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

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Submitted
24 Dec 2018
Accepted
21 Jan 2019
First published
25 Jan 2019

Dalton Trans., 2019,48, 7090-7093
Article type
Communication
Author version available

One-dimensional magnetic chain composed of CuII and polychlorinated dipyridylphenylmethyl radical: temperature-dependent Jahn–Teller distortion correlated to π-conjugation and magnetic properties

S. Kimura, H. Uchida, T. Kusamoto and H. Nishihara, Dalton Trans., 2019, 48, 7090
DOI: 10.1039/C8DT05104F

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