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Metallopolymers cross-linked with self-assembled Ln4L4 cages

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Abstract

Herein, we fabricated a hybrid PDVB-Ln4L4 metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

Graphical abstract: Metallopolymers cross-linked with self-assembled Ln4L4 cages

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Publication details

The article was received on 20 Dec 2018, accepted on 22 Feb 2019 and first published on 23 Feb 2019


Article type: Communication
DOI: 10.1039/C8DT05015E
Citation: Dalton Trans., 2019, Advance Article

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    Metallopolymers cross-linked with self-assembled Ln4L4 cages

    Q. Yan, L. Zhou, H. Zhou, Z. Wang, L. Cai, X. Guo, X. Sun and Q. Sun, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT05015E

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