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Redox chemistry of an anionic dithiolene radical

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Abstract

The redox chemistry of the first stable anionic dithiolene radical was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of by Ph3C+BF4 (or O2) conveniently gives 4, the neutral dithiolene dimer.

Graphical abstract: Redox chemistry of an anionic dithiolene radical

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Publication details

The article was received on 18 Dec 2018, accepted on 07 Feb 2019 and first published on 07 Feb 2019


Article type: Communication
DOI: 10.1039/C8DT04989K
Citation: Dalton Trans., 2019, Advance Article

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    Redox chemistry of an anionic dithiolene radical

    Y. Wang, Y. Xie, P. Wei, H. F. Schaefer and G. H. Robinson, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04989K

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