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Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

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Abstract

Molybdenum triiodide complexes bearing various substituted pyridine-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward the reduction of nitrogen gas into ammonia under ambient reaction conditions.

Graphical abstract: Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

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Publication details

The article was received on 18 Dec 2018, accepted on 21 Jan 2019 and first published on 21 Jan 2019


Article type: Communication
DOI: 10.1039/C8DT04975K
Citation: Dalton Trans., 2019, Advance Article

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    Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

    T. Itabashi, I. Mori, K. Arashiba, A. Eizawa, K. Nakajima and Y. Nishibayashi, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04975K

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