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NOx anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

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Abstract

Nitrate and nitrite anions have multifaceted impacts on the environment and human health. We herein report selective recognition of nitrite over nitrate anion inside the cavity of bimetallic azacryptates having p-xylyl spacers. This work reveals a number of binding interactions which play pivotal roles in nitrite anion recognition by rigid metal cryptates.

Graphical abstract: NOx− anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

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Publication details

The article was received on 18 Dec 2018, accepted on 04 Feb 2019 and first published on 04 Feb 2019


Article type: Communication
DOI: 10.1039/C8DT04971H
Citation: Dalton Trans., 2019, Advance Article

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    NOx anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

    T. Chattopadhyay, A. B. S., S. Gupta, A. S., J. A. Bertke and S. Kundu, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04971H

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