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Teaching c-phosphanylimines the titanaaziridine coordination mode

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Abstract

The c-phosphanylimine L1 was employed for the synthesis of the novel titanaaziridine 1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c-phosphanylimines and compound 1 is the first group 4 complex featuring a c-phosphanylimine ligand.

Graphical abstract: Teaching c-phosphanylimines the titanaaziridine coordination mode

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Publication details

The article was received on 14 Dec 2018, accepted on 16 Dec 2018 and first published on 17 Dec 2018


Article type: Communication
DOI: 10.1039/C8DT04918A
Citation: Dalton Trans., 2019, Advance Article
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    Teaching c-phosphanylimines the titanaaziridine coordination mode

    M. Fischer, H. Steinert, M. Schmidtmann and R. Beckhaus, Dalton Trans., 2019, Advance Article , DOI: 10.1039/C8DT04918A

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